Companies are not compatible with ÖkoVision if they produce, promote, trade, distribute, use (in significant
quantities), or enable or promote the manufacture, trade, or use of halogenated
organic substances.
As a principle, ÖkoVision
does not invest in such companies. The
criterion is very important but not absolute, and attenuating circumstances are
considered in judging businesses (see below for detail).
The criterion is about
organic chemical substances or compounds, in which one halogen atom or several
same or different halogen atoms form direct bonds with carbon. Of concern are mass products of the chemical
industry, such as PVC or halogenated solvents, and specialized chemicals, such
as pesticides or biocides. The criterion
does not apply to pharmaceutical and
other substances that produce large benefits with the use of small quantities,
and for which no practical substitutes exist.
Reasoning:
In chlorine chemistry ("Chlorchemie")
or more widely "halogen-organic chemistry", substances are produced
or used, in which a chemical bond exists between halogen atoms – fluorine,
chlorine, bromine, or iodine – and carbon atoms. All substances with a halogen-carbon bond
and/or their biochemical or physical metabolites and degradation products are
highly toxic, eco-toxic, carcinogenic, teratogenic, act as greenhouse gases and
aggravate climate change and/or are damaging to the Earth‘s protective ozone
layer.
While some substances can
be used in small quantities in medicine, where the benefits for humans outweigh
the costs and damages, most such substances are so harmful in their
manufacture, use, and disposal that cost-benefit assessments should stop their
production, sale and trade. Even if some
halogenated organic substances are not hazardous per se, they become so when
they react or degrade, for instance when incinerated, exposed to light or natural
ultraviolet rays (in the stratosphere).
The production of halogenated organic substances is hazardous; notorious
large accidents in the chemical industry, such as at Bhopal, Schweizerhalle
(Sandoz), or Toulouse, involve, as a rule, this class of chemicals. Chlorine chemistry is an obstacle to the
development of a sustainable and ethical industrial society and market economy.
Chemical Background:
Halogens, the elements
"born from salt" or "forming salt", form a group in
chemistry‘s periodic table: Fluorine (F – no. 9 in periodic table), chlorine
(Cl – 17), bromine (Br – 35) and iodine (I – 53)[1].
Their high chemical bond
energy (or electronegativity or redox potential) is the key characteristic of
halogens. Fluorine has the highest chemical
bond energy of all elements[2], and bond
energy declines within the group from fluorine to iodine. Each atom is lacking one electron in its
outermost shell; they strongly seek to gain one electron and complete that
shell (which charges them negatively or reduces them). This characteristic makes elemental halogens
extremely reactive; they can break up many chemical compounds and form new ones
with particular properties of concern.
Some of the newly formed compounds are themselves very stable, while
others are not.
Chemical Policy Background:
"Chlorchemie" symbolises
a chemical policy controversy, at the heart of which are the manufacture, use,
recycling (or better "down-cycling") and the (highly problematical)
disposal of polyvinylchloride (PVC) and other mass or bulk products of the
chlorine chemical industry. Ozone-depleting
chlorinated or halogenated hydrocarbons are also part of the controversy. There are also a range of substances for
special purposes as industrial chemicals or, for instance, as insecticides or
fungicides.
It is known since 1885/1890
how pure chlorine on the one side and on the other potassium or sodium hydroxide
can be produced using electrical energy (chloralkali electrolysis), where chlorine
and potassium viz. sodium are always produced in fixed proportion (combined
production). The objective was (and to a
degree still is) the production of potassium and sodium; chlorine emerges as a
dangerous by-product (or waste), which has to be chemically bonded and
stabilised before it could be disposed of (in landfills). This was done by bonding of chlorine as
chloroethene or vinyl chloride (C2H3Cl), which was then
used to synthesise long-chained polyvinylchloride (PVC [C2H3Cl]n)
for landfilling. PVC is still quite
unstable, and in its decay releases the aggressive and corrosive chlorine. For this reason, PVC was further stabilised
with additives such as cadmium, and through the addition of plasticisers, such
as a partly endocrine phthalates, was given properties that allowed PVC to be
sold as a product.
The generation of combined
products and by-products is a common feature of the chemical industry. Not all such products can be put to good use.
Often the exact composition of mixtures
of such products is not known, and the separation of mixtures would be too
cumbersome and expensive. In such cases,
initially in the interest of plant safety, mixtures with unknown or uncertain
composition and characteristics were "fully chlorinated" or
"fully halogenated" and thus homogenised. This method of waste treatment produces large
quantities of mostly short-chained halogenated alkanes[3], the
fluoro-chloro-hydrocarbons (CFC), which have known properties and could be
marketed as solvents, cooling agents, or propellants for spray cans, for
instance. Fully halogenated hydrocarbons
are chemically very stable, no longer reactive, and thus very durable. However, they rise to the stratosphere where
they decay under the exposure to high-energy radiation from space and then
damage the Earth‘s stratospheric ozone layer that protects life from the
radiation.
Chlorine chemistry is a
history of converting hazardous waste into hazardous yet marketable products.
Another aspect drives the
continuing chemical policy controversy in addition to the history and the
dangerous properties of the products of the chlorine chemical industry: The production of chlorine and other halogens
as feed-stock for the halogen-organic chemical industry requires enormous
quantities of electrical energy. For
this reason, chloralkali electrolysis plants and nuclear power plants are found
next to one another, with the chemical industry benefitting more or less
directly from the subsidies and privileges given to nuclear power plants.
The "Dirty Dozen" and the "Nasty
Nine":
Chlorine and other halogens
are prominent also in the "Dirty Dozen" and "Nasty Nine"
regulated (or banned) by the Stockholm Convention.
These are "persistent organic pollutants" or "POPs", namely
dangerous insecticides, a fungicide, industrial chemicals and pollutants from
combustion plants.
What this is not about:
The chemical bonds between
halogens and carbon are at the core.
Chemical bonds with other elements of the carbon group or metals are not
relevant here. Not part of the
controversy and thus not in focus here are inorganic halogen bonds, mostly
salts. Sodium chloride (NaCl) is cooking
salt and on everyone‘s lips, and the halogens are important for human health
(fluorine for teeth, iodine for the thyroid gland, …). Industry lobbyists like to stress that
"chlorine is not dangerous", as it is part of food. The argument is designed to distract from the
dangers cause by halogen-organic compounds.
Halogens also form bonds
with other elements that are similar to carbon.
An example is silicon, and silicon chloride plays a role in
semiconductors and the production of solar panels. Although such compounds can be problematic,
they are not part of the chlorine chemistry controversy.
[1] There
is also the rare, radioactive astatine (At – 85) and the artificial or man-made
and highly unstable ununseptium (Uus – 117).
These are without practical relevance here.
[2] As a
consequence, no other chemical element can break the chemical bonds formed by fluorine,
and physical energy in the form of electricity must be used to form pure fluorine
(F2); producing meaningful quantities of pure halogens requires
energy-intensive technical processes at industrial scale.
[3] Alkanes are chains of carbon atoms, which in their basic
form are surrounded only by hydrogen (hydrocarbons); methane (CH4)
and ethane (C2H6) are most relevant here.